Estudios teóricos y experimentales de la reactividad 1,3-dipolar de heterociclos mesiónicos y azidas

  1. Cantillo Nieves, David
Supervised by:
  1. Martín Ávalos González Director
  2. José Luis Jiménez Requejo Director

Defence university: Universidad de Extremadura

Fecha de defensa: 18 February 2011

Committee:
  1. Joaquín Plumet Ortega Chair
  2. José Luis Bravo Galán Secretary
  3. Isabel María Gómez Monterrey Committee member
  4. Manuel Bueno Martínez Committee member
  5. Jose Albertino Almeida Figueiredo Committee member

Type: Thesis

Teseo: 302977 DIALNET lock_openOpen access editor

Abstract

This work deals with the reactivity of two types of mesoionic heterocycles (münchnones and thioisomünchnones) with dipholarophiles. The reaction mechanisms have been explored through DFT calculations. The preparation of triazoles and tetrazoles by l,3-diploar cycloaddition of azides with alkynes and nitriles, respectively, is also treated.