Rhodium-catalyzed intermolecular C–H amination of simple hydrocarbons using the shelf-stable nonafluorobutanesulfonyl azide

  1. José Ramón Suárez 1
  2. Jose Luis Chiara 1
  1. 1 Instituto de Química Orgánica General, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain
Revista:
Chemical Communications

ISSN: 1359-7345,  1364-548X

Any de publicació: 2013

Volum: 49

Número: 80

Pàgines: 9194-9196

Tipus: Article

DOI: 10.1039/C3CC44594A GOOGLE SCHOLAR lock_openAccés obert editor

Altres publicacions en: Chemical Communications

Resum

A new procedure has been developed for the direct intermolecular C–H amination of simple hydrocarbons using shelf-stable nonafluorobutanesulfonyl azide in the presence of a dirhodium(II) tetracarboxylate catalyst under mild reaction conditions. Some mechanistic details are briefly discussed on the basis of control experiments.

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